The pros and cons of nitrile rubber, NBR or Buna-N

Nitrile, Buna-N or NBR rubber is a widely used elastomer, thanks in large part to its highly oil & fuel resistant properties and tensile strength. In this article, Martin’s Rubber Company explains more about the properties, applications, pros and cons of this versatile rubber material.   Nitrile rubber is a synthetic rubber copolymer of acrylonitrile (ACN) and butadiene that you may know better under trade names like Nipol, Krynac and Europrene N. Why might you consider specifying nitrile for your application? Let’s find out, with a closer inspection of this rubber material.

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What is Buna-N?

Nitrile (also known as NBR rubber and Buna-N) is the seal industry’s most widely used and economical elastomer. This is partly because it displays excellent resistance to petroleum-based oils, fuels, water, alcohols, silicone greases, hydraulic fluids. However, it also has a good balance of desirable working properties like low compression set, high abrasion resistance and high tensile strength.

NBR rubber properties

Nitrile is a family of unsaturated copolymers of 2-propenenitrile and butadiene monomers (1,2-butadiene and 1,3-butadiene). Its physical and chemical properties vary depending on the polymer’s composition of nitrile. The more nitrile there is within the polymer, the higher its resistance to oils but the lower its flexibility. Nitrile rubber is more resistant than natural rubber to oils and acids, and has superior strength, but suffers from inferior flexibility.

Where is nitrile used?

Nitrile rubber is used in a wide variety of applications, such as O-rings, gaskets, oil seals, automotive transmission belts, hoses, V belts, synthetic leather, disposable non-latex gloves, printer’s form rollers and cable jacketing. NBR latex can also be used in the preparation of adhesives or as a pigment binder.

Pros and cons of Buna-N

Nitrile offers the following advantages:

• Excellent abrasion resistance.
• Good rebound.
• Good tear resistance.
• Good non-polar solvent resistance.
• Good water resistance.
• Good oil resistance.
• Cheaper than fluoroelastomers

Nitrile suffers from the following disadvantages:

• Poor ozone, sunlight, and weather resistance.
• Limited high temperature resistance.
• Poor flame resistance.

Nitrile rubber products from Martin’s Rubber

Speak to one of our advisers today to find out more about our nitrile rubber manufacturing capabilities. We can talk you through your options and give you honest and informed guidance to help you to specify the ideal product for your application. Speak to us today on 023 or [ protected]. For more information on why nitrile rubber is so popular for heat resistance, see our post: Why Buna N is so popular for use with hydrocarbons.

If you are looking for more details, kindly visit NBR O Ring.

When it comes to selecting the right material for seals, gaskets, and O-rings, two common choices in the rubber industry are Nitrile Butadiene Rubber (NBR) and Hydrogenated Nitrile Butadiene Rubber (HNBR). Both materials are renowned for their durability and versatility, but they offer distinct advantages depending on the application. This guide will help you understand the differences between HNBR and NBR and how to choose the right one for your needs.

What is NBR?

Nitrile Butadiene Rubber (NBR), also known as Buna-N or simply nitrile, is a synthetic rubber copolymer made from acrylonitrile and butadiene. NBR is well-regarded for its excellent resistance to petroleum-based oils and fuels, making it a popular choice in automotive, aerospace, and industrial applications.

Key Characteristics of NBR:

• Oil and Fuel Resistance: Exceptional resistance to petroleum-based oils and fuels.
• Temperature Range: Typically ranges from -40°C to +120°C (-40°F to +248°F).
• Abrasion Resistance: Good wear and tear resistance.
• Cost-Effective: Generally more affordable than HNBR.

What is HNBR?

Hydrogenated Nitrile Butadiene Rubber (HNBR) is a derivative of NBR that has been hydrogenated to improve its physical and chemical properties. The hydrogenation process significantly enhances its resistance to heat, ozone, and various chemicals, making HNBR a superior choice for more demanding applications.

Key Characteristics of HNBR:

• Enhanced Temperature Range: Can withstand temperatures from -40°C to +150°C (-40°F to +302°F), and in some cases even higher.
• Chemical Resistance: Superior resistance to a broader range of chemicals, including ozone and oxidizing agents.
• Mechanical Properties: Improved tensile strength, elongation, and abrasion resistance compared to NBR.
• Longevity: Increased durability and lifespan in harsh environments.

Comparing NBR and HNBR

Temperature Resistance

• NBR: Suitable for applications with moderate temperature requirements.
• HNBR: Ideal for high-temperature applications, maintaining flexibility and performance in extreme conditions.

Chemical Resistance

• NBR: Good resistance to oils and fuels but less effective against ozone and oxidizing agents.
• HNBR: Excellent resistance to a wide range of chemicals, including ozone, making it suitable for outdoor and high-chemical exposure applications.

Mechanical Properties

• NBR: Offers good mechanical properties, including abrasion resistance.
• HNBR: Enhanced mechanical properties, providing better tensile strength and elongation.

Cost

• NBR: More cost-effective, making it a preferred choice for applications where high-performance characteristics are not critical.
• HNBR: Generally more expensive due to the additional hydrogenation process and improved performance benefits.

Application Longevity

• NBR: Adequate for many standard applications but may degrade faster in harsh conditions.
• HNBR: Longer lifespan in demanding environments, reducing the need for frequent replacements.

Choosing the Right Material

The choice between NBR and HNBR depends on the specific requirements of your application. Here are some factors to consider:

• Operating Temperature: If your application involves high temperatures, HNBR is the better choice.
• Chemical Exposure: For environments with exposure to ozone, oxidizing agents, or aggressive chemicals, HNBR offers superior resistance.
• Budget Constraints: NBR is a cost-effective option for applications with less demanding conditions.
• Mechanical Stress: For applications requiring high tensile strength and durability, HNBR's enhanced properties are advantageous.

Conclusion

Both NBR and HNBR are versatile and reliable materials with their unique strengths. Understanding the differences between these two types of rubber can help you make an informed decision, ensuring optimal performance and longevity for your seals, gaskets, and O-rings. Whether you choose NBR for its cost-effectiveness and oil resistance or HNBR for its superior temperature and chemical resistance, selecting the right material is crucial for the success and reliability of your application.

For more information, please visit Fork Oil Seal.